High nitrogen increases the pH of the must and wine, increasing the malate concentration in grape juice. Too much available nitrogen on the other hand can create strong canopy growth, increasing shading and wine pH.
Influencing grape and wine pH
The pH of the juice/must affects the taste, sugar/acid balance and stability of wines. It is determined by the balance of the major anions (malate and tartrate) and presence or absence of major cations (mainly potassium). Harvest timing and management also effects wine pH. The pH can increase by as much as 0.2 units between harvest and delivery.
High pH values can alter the colour of anthocyanin solutions – responsible for red wine colour - by changing the structure of the anthocyanin molecule. A high pH must, results in wines that have a flat taste and red wines with a brownish colour. Generally, a pH above 3.6 is undesirable as it can have a negative effect on a range of wine quality characteristics
Crop Nutrition and Grape and Wine pH
Nitrogen
Potassium
There is a strong relationship between potassium and grape and wine pH. Too much potassium results in a high wine pH and a poorer quality wine.